High chromium white iron, in the form of castings and weld overlays, is one of the alloys used to improved wear resistance and equipment longevity. Pdf abrasive wear behavior of high chromium cast iron and. High chromium white cast irons are an important class of wear resistant materials. Investigation of the wear resistance of high chromium white irons. The invention discloses a highchrome wearresistant cast iron material and a heat treatment method. High chromium iron is recommended for applications which involve both corrosion and abrasion. The 25% cr alloy is the most common high chrome white iron poured at penticton foundry. The present invention relates to the heat treating method of a kind of highchromium wearresistant white cast iron cr28, be specifically related to a kind of highchromium wearresistant white cast iron cr28 heat treating method in working life that improves. The silicon element decreases the hardenability of the highcr white cast iron. This specification covers the standard for ironchromiumnickel, highalloy tubes made by the centrifugal casting process intended for use under pressure at high temperatures. Pdf abrasive wear behavior of high chromium cast iron.
Highchromium irons almost dont concede in fluidity to regular gray cast iron that allows using parts sufficiently difficult form. Development of wear resistant highchromium cast iron carbon fecr development of the chromium cast iron was grounded in the system of 1822 wt. Solid particle erosion and erosioncorrosion of materials. Wear resistance of high chromium white cast iron for coal grinding. The microstructure of this high chromium iron was studied using metallurgical optical microscopy om and compared to the hadfield steel. When a martensitic white iron is desired for superior abrasion resistance, additions of 0. A novel method to extract iron, titanium, vanadium, and. The structure of high chrome white iron is made up of martensite, with carbides that are formed during solidification via precipitation from the liquid metal while a eutectic reaction is taking place. Mathematical analysis permits quantitative and qualitative assessment of the phase composition of alloys. The alloys investigated were hypereutectic and hypoeutectic high chromium white iron castings, a hypereutectic high. Highchromium white cast irons are ferrous alloys containing 1% cr and 1. The silicon element decreases the hardenability of the high cr white cast iron.
Effect of heat treatment on microstructure and properties of semi. Steel castings handbook supplement 7 welding of high alloy castings. A novel process for the extraction of iron, titanium, vanadium, and chromium from highchromium vanadiumbearing titanomagnetite concentrates is proposed. The study was carrying out on samples cut from the casting.
The present invention relates to the heat treating method of a kind of high chromium wearresistant white cast iron cr28, be specifically related to a kind of high chromium wearresistant white cast iron cr28 heat treating method in working life that improves. The tubing shall be supplied in the as cast condition or as cast with machining on the outside or inside surfaces. Hightemperature erosion high chromium white cast iron cr contents type of carbide a b s t r a c t this present study investigated effect of chromium content on high temperature erosive. High chromium cast irons are widely used as abrasion resistant materials. Jan, 2016 the 25% cr alloy is the most common high chrome white iron poured at penticton foundry. Their exceptional wear resistance is the result of their high carbide content, which forms along with austenite during solidification as a proeutectic or eutectic phase depending on alloy composition, and particularly depending upon carbon and chromium content.
Abrasion resistance of ascast highchromium cast iron in. Alloy data sheet high chrome white iron 25% penticton. Their properties and wear resistance depend on carbides and on the nature of the matrix supporting these carbides. The mechanical properties of high chromium cast irons are better than those of the high silicon cast irons. Chapter 1 high chromium cast irons chiang mai university data of the parameters of heat treatment of high chromium cast iron, and optimal conditions for heat treatment was proposed for casts of similar properties and parameters. Iijima 3 grain boundary diffusion of iron, cobalt and chromium in high purity iron. Microstructure of vanadium, niobium and titaniumalloyed. Wear resistance of high chromium white cast iron for coal. The average grade of the metallurgical chromite ore was 43.
Highchromium irons have good mechanical properties, high hardness in a cast state, low fluctuation of hardness when properties change. Microstructure and properties of high chromium cast irons. Research article heat treatment in high chromium white cast. About iron chromium alloy iron chromium is one of numerous metal alloys sold by american elements under the trade name ae alloys. Pdf the influence of heat treatment on microstructure and mechanical properties of high chromium white cast iron alloyed with titanium was. In the present work, additions of 2% vanadium, 2% niobium and 2% titanium were respectively made to a highchromium white iron 17% cr to analyse the effect of these elements on the ascast structure of the alloy, and their influence on the materials hardness. Microstructure and wear resistance of high chromium cast iron containing niobium li wei male, born in 1963, ph. Relative erosioncorrosion wear rate of fe15 to 30cr3c has been reported. D gb m 3 s1 grain boundary diffusion in high purity iron the magnetic influence was observed for the first time grain boundary diffusion in high purity iron the. Microstructural characteristics and mechanical properties of. The microstructure of this highchromium iron was studied using metallurgical optical microscopy om and compared to the hadfield steel. This alloy has great abrasion resistant properties especially against gouging, grinding and scratching.
Standard specification for centrifugally cast iron. The study led to systemize the literature data of the parameters of heat treatment of high chromium cast iron, and optimal conditions for heat treatment was proposed for casts of similar properties and parameters. Due to their excellent wear resistance in aggressive environments, high chromium cast irons hccis are widely used in industrial applications. On the comparison of microstructure characteristics and. The properties related to the service performance of the hccis containing niobium, namely the abrasion resistance in wet application and impact toughness were also examined. The high temperature corrosion of different iron aluminides and iron. Effect of niobium on the microstructure of high chromium. Pdf the article presents results of heat treatment on the high chromium cast iron. Highchromium white cast iron is a material highly used in mining and drilling shafts for oil extraction, due to its high wear resistance. It also has excellent growth and scaling resistance under oxidising conditions. Microstructural modifications of ascast highchromium white iron by heat treatment. Lessinformationcanbefound for the wear behaviour of high chromium cast irons in wet conditions with corrosive media. Cn102899469b heattreatment method of highchromium wear. The high chromium cast irons respond to heat treatment when the carbon and chromium contents are appropriately adjusted.
Cr 23 mo 0 ni 0 cu 0 five samples with dimensions o15. Even though they have good strength properties, they also have limited machinability. High chromium white cast iron alloy used in coal grinding components is a material that may present different wear resistance depending on the thermal treatment used in its manufacturing. Microstructural modifications of ascast highchromium. The role of retained austenite on the performance of high. Chemicalgrade chromite ore generally ranged from 40 to 46 pct cr2o3 with a chromium to iron ratio of 1. The distribution of chemical elements over the area of the corresponding metallographic image is shown for the example of copper, which is extremely nonuniformly distributed, even within a single grain. The cutting tools selection on machining high chromium cast iron. Analysis of the high chromium cast iron microstructure after. High chromium cast iron samples were prepared and melted in a magnesia crucible in an electric resistance furnace that can be rapidly heated up to temperature.
Highchromium cast iron an overview sciencedirect topics. Highchromium 2234 per cent cast iron alloys and their. Microstructural modifications of ascast highchromium white. A novel process for the extraction of iron, titanium, vanadium, and chromium from high chromium vanadiumbearing titanomagnetite concentrates is proposed. Microstructural characteristics and mechanical properties. Since a high chromium content is essential to maximum corrosion resistance, any area that has been depleted. In this study, high chromium white iron hcwi alloy and the hadfield steel were studied. Molybdenum is even more effective when used in combination with copper, chromium, nickel, or both chromiumandnickel. The highchrome wearresistant cast iron material is prepared from iron as a main raw material, and carbon, silicon, manganese, sulphur, phosphorus, chrome, molybdenum, nickel and copper as auxiliary materials in manners of melting and casting after preparation. In mining, wear is caused by operational problems in which generate high costs. Generally immediately available in most volumes, ae alloys are available as bar, ingot, ribbon, wire, shot, sheet, and foil. The influence of heat treatment on microstructure and mechanical properties of high chromium white cast iron alloyed with titanium was investigated. High chromium cast iron, heat treatment, hardening, tempering, soft annealing 1. Effect of heat treatments and alloying additions article pdf available in international journal of cast metals research 226.
Steel castings handbook supplement 7 welding of high. Grain boundary diffusion of fe in high purity iron 1026 1024 1022 1020 1018 1016 0. Introduction high chromium white cast irons containing 12 to 30wt. In this context, the properties of this alloy, containing 22% chromium and 3% carbon, were investigated after applying different heat treatments and. They are recommended for a ph range of 2 to 11 where erosives are present. Pdf heat treatment in high chromium white cast iron ti alloy. The paper presents test results of irons which contain in wt. The carbide types known to be present in the high chromium cast irons are m7c3, m 3c, m 23 c6 and m 6c, with increasing m. Abrasive wear behavior of high chromium cast iron and hadfield steela comparison. In the ascast condition, the microstructure of high chromium molybdenum white iron consists essentially of dendrites of austenite in a matrix of eutectic mixture of austenite and fe, cr 7 c 3 carbides.
The heat treating method of a kind of highchromium wearresistant white cast iron cr28. Pdf microstructure and properties of high chromium cast. The high chrome wearresistant cast iron material is prepared from iron as a main raw material, and carbon, silicon, manganese, sulphur, phosphorus, chrome, molybdenum, nickel and copper as auxiliary materials in manners of melting and casting after preparation. Research article heat treatment in high chromium white. Microstructure and wear resistance of high chromium cast. The typical chemical requirements of various grades and class of alloys castings available in the market are given in table 172. Separate part of paper was devoted to discuss the bimetallic castings with chromium cast iron layer as well as typical applications of chromium cast iron castings in minig, proccesing, metallurgical and power industry. The samples were cut from the casting made from chromium cast iron, with the chemical composition shown in table table 2. Hc28 alloy is particularly well suited for slurry pump parts and pipe fittings in coal prep operations and coal fired power stations. Microstructure and wear resistance of high chromium cast iron.
The highchromium cast irons respond to heat treatment when the carbon and chromium contents are appropriately adjusted. The heat resistant alloys are generally higher in alloy content than the. Steel castings handbook supplement 7 welding of high alloy. Alloy data sheet high chrome white iron 25% penticton foundry. Heat treatment in high chromium white cast iron ti alloy. High chromium white irons, astm a532 are considered not weldable. Investigation of the wear resistance of high chromium. Pdf analysis of the high chromium cast iron microstructure after. Pdf heat treatment in high chromium white cast iron ti. High chromium white irons are ferrous based with the main alloying additions being 15 wt% chromium and 1. However, machining of these alloys is very difficult. Microstructure and erosioncorrosion behaviour of ascast high chromium white irons containing molybdenum in aqueous sulfuricacid slurry was studied. High chromium irons description high chromium irons provide excellent erosion resistance and a reasonable degree of corrosion resistance due to their high alloy content, thus surpassing all other cast irons for use in aggressive services.
However, these high chromium irons have a white iron structure. The type and morphology of the eutectic carbides in high chromium cast iron depend upon both chemical composition and solidification rate 3, 14, 2426. In the present work, additions of 2% vanadium, 2% niobium and 2% titanium were respectively made to a high chromium white iron 17% cr to analyse the effect of these elements on the ascast structure of the alloy, and their influence on the materials hardness. Metallurgical and materials transactions aphysical metallurgy and materials science, 2712. Part 1 machining high chromium cast iron and the cutting tools selection. The role of retained austenite on the performance of cast iron based grinding media balls is somewhat controversial. The heat treating method of a kind of high chromium wearresistant white cast iron cr28. Grain boundary diffusion of iron, cobalt and chromium in. Pdf casting process design and wear properties of a high.
The hardness and unnotched charpy impact strength of the hcwi alloy and hadfield steel were examined at ambient tem. This study was carried out for different solidification rates, so the alloys were cast into wedgeshaped copper moulds. Some researchers studied white cast iron alloys with high chromium and the addition of niobium for wear plates manufacturing and therefore, plates to protect structural parts of the equipment have been developed. High temperature erosion high chromium white cast iron cr contents type of carbide a b s t r a c t this present study investigated effect of chromium content on high temperature erosive. Analysis of the high chromium cast iron microstructure. High chromium cast irons hccis are alloys containing 1530 wt. High temperature corrosion behaviour of iron aluminides. In this communication, the initial results of an investigation to use niobium as an alloying element in highchromium irons are described. The cutting tools selection on machining high chromium. Learn more about chromium uses, effectiveness, possible side effects, interactions, dosage, user ratings and products that contain chromium.
Improvement of abrasive wear resistance of the high chromium cast. Cn104195420a highchrome wearresistant cast iron material. Highchromium irons almost dont concede in fluidity to regular gray cast iron that allows using parts sufficiently difficult form directly after casting without the following machining. Alternatives to welding chrome white iron astm a532. High chromium white cast irons are ferrous alloys containing 1% cr and 1.
The invention discloses a high chrome wearresistant cast iron material and a heat treatment method. Hc28s abrasion resistance is comparable to chromenickel irons astm a532 class. One school of thought is that retained austenite improves the performance through work hardening and transformation to martensite. His research interests mainly focus on abrasion metallic materials and metal matrix composites, special functional metallic materials, tribological research and biomedical materials.
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